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What is metamerism?

If you are color matching a green color from your competitor, let say you are using blue and yellow color to get the required green color while your competitor is using a green pigment colorant to get the green color, then high chances is that when you placed your color panel and competitor panel side by side and view them under different light source in the light box,
you will notice the color is not the same under different light source or it might look the same at one light source but not the same on another light source, this is what we call metamerism.

 

When check on a color, the followings are required:

    A light source - illuminating an object.
    An object - reflecting light to an observer.
    An observer - sensing/checking the reflected light.

If you check on the color spectrophotometer, you will notice that your panel and competitor panel will have different graph curves as the pigments used in your panels and your competitor panel is not the same, even thought the end result is a green color.Your color panel and competitor color panel that show metameric exhibit the following:
    They have different spectral reflectance factors
    They do not match under at least one combination of illuminant and observer.

There are two types of metamerism; illuminant and observer. Either one can result in unacceptable colored products.
·    Illuminant Metamerism - where metamerism results from changes in illuminants, and where the observer does not change in this case.
·    Observer Metamerism - this is where metamerism results from changes in observers, and where the illuminant does not change.
Illuminant metamerism occurs when a pair of objects match under one light source, but do not match under one or more other light sources. This can result in products that match under production light conditions,  but do not match under light sources where they may be sold and/or utilized. Observer metamerism occurs when a pair of objects match for one observer, but do not match for another. This situation can occur when production matching is done under one of the CIE observers, and subsequent evaluation done under the other. It also can occur in visual product assessment situations where the color sensitivity and also on how one judge color differ from one another.

How Do We Detect Metamerism?
The followings are the two common test that are use to check on the color metamerism effect.

Visual Test for Metamerism
Please follow the following steps:
 1)   Confirm that the color match, by viewing (in a light booth) under the agreed upon primary light source.
 2) Change the light source to a test source which is different from the reference source.
 3) If the objects still match, then it is likely that they will match under any source, and are thus probably not metameric. If the objects do not match under the test source, then they are a metameric pair.
                

Instrumental Test for Metamerism
Please follow the following steps:
 1) Using a spectrophotometer, measure the objects, and record the L, a, b value
 2) Compare their reflectance spectral curves. If the curves differ, and cross each other at least three times, then the objects are metameric.
 3) Confirm the metamerism and compute its amount, by calculating color differences Delta E under different illuminant/observer combinations. 

If your spectrophotometer able to show the Delta E under 3 different light sources in one screen, try to check the L, a, b value is positive or negative value across the 3 different light sources or not, for example, if we compare the "a" value is all show positive value for the 3 light sources respectively, we are quite sure that the "a" value is not causing the metamerism, however if we compare the "b"value for the following example:

                                light source1    light source 2    light source 3
        a value        +0.33                  +0.48                +0.53
        b value        +0.5                    -0.43                 +0.35
                  
        You will notice that "b" value is the one that contribute to the metamerism.

How Can We Reducing the Effects of Metamerism ?
Try reduce the metamerism effect by apply the following methods/steps:
1) Use the same pigment colorants in the formulation to color match, in the given example, if we knew competitor is using green pigment colorant to match the green color, try follow the same and do not use yellow and blue colorant to get the green color.
2) Substituting working standards for the original metameric standard, whenever possible in the control and acceptance processes. It is common that your customer may provide you with competitor’s color panel to match, made sure once the color approve by them, your customer should have your new standard for the same color.
3) Do not try to add new colorant to exiting production color batch , in which the standard panel was prepared without the new colorant.

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The newsletter for this month is out, check out the link from your email. This month the formula is about foam adhesion coating. This newsletter is only for those who had joined coating formula guide member community. Joining is free, if you have not join, what are you waiting for? Take action now!

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Yes, that’s right, this is only exclusive for members who had signed up for our newsletter. The newsletter is send out to the member’s registered email account respectively. For information, this month newsletter focus on epoxy clear coating. Some of the member might not have receive the newsletter because some of the member had signed up after we had sent out the newsletter. If you need more free formula guide, don’t forget to sign up for our newsletter.

The Coating Formula Guide team would also like to take this opportunity to thank those that had supported this website, especiall for this year 2008. We hope to continue receive your support for 2009.

Once again, we wish everybody Happy and Succesfull 2009.

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Introduction

Epoxy resin contains some hydroxyl groups along the molecular chain and 2 epoxide rings at the ends of the molecule, however, the novolac type contains more than two epoxide rings. Cross-linking  take place through the reactive hydroxyl groups and epoxide ring. The common epoxy that use in coating are epoxy resin, epoxy –ester and other epoxidized resin. Most of the epoxy coating is cure via stoving, however, epoxy flooring is cure via air drying.

 
Common Usage

Epoxy coating is used in many industry, mainly for internal purpose as it did not have good outdoor durability. The epoxy clear is use in can coating, it is apply onto the inner wall of the can. Epoxy primer has been use in coil coating for cost effective purpose, while epoxy top coat can use as foam adhesion backer in building panels. It is also common use in uv-cure wood coating. Another major usage of epoxy is in floor coating.

 

Cross-linking  With Other Resin

Epoxy resin can be cross link with:

 

1)      Hydroxyl group-like those phenolic and amino resin

2)      Cationic  self-polymerization and uv-curing

3)      Nitrogen resin or polyamide a-common in powder coating and epoxy floor coating



Epoxy use in uv-curing is 100% solid by itself even though it does look like a solvent base resin. The high molecular weight epoxy like the Epikote 1007 and 1009 are supply in resin chip form.  The epoxy can be in water-based version. The epoxy resin is emulsified with surfactant. The material, for example, urea formaldehyde resin emulsified with it to produce a stoving coating or a 2k water soluble poly-amide for air drying at room temperature.

Watch out for the next post on epoxy formulation…..do come back and check it out.

 

 

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If you had read our post few days ago regarding the coating and formula guide team will visit this coating show, we did visit it indeed, but we are kind of disappointed with the small size of it. A visitor  informed that he can "finished" checking most of the booth in 30 mins as there are not much exhibitors. Multi National Company like Ciba is not participate in this coating show.

Well, if compare the Chinacoat,  this Asia Pacific Coating definitely unmatch in term of its number of exhibitors and visitors. Let hope that the next Asia Pacific Coating Show at Bangkok will have more booth and visitor.

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This year, the Asia Pacific Coatings Show will be held at Kuala Lumpur, Malaysia. The venue for this coating show is Kuala Lumpur Convention Centre, which is very near to the famous Petronas Twin Tower.

 

Petronas Tower

The show will start next week on the 24th June til 26th June. Of course not to be missed is the coating conference held every year during the coating show. This year, the conference title is"Organic Coating:New  Performances and Developments". Do check out the conference material by BYK , Worlee and Rhodia respectively.

Visitor can pre-register online or register on the spot during the coating show. Registered guest will be provide a tag which can be use during the 3 days of the coating show.

Coating Formula Guide team will attend this coating show and will collect the latest coating technology information, new raw material and many more from this coating show. Do check out for more post from us!!

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Do You dislike high gloss finishes? What is the required to lower the gloss?

  

White powder

 

The most common way to lower the gloss is to use matting agent. The matting agent can be in the form of powder which required paint supplier to disperse it, and it is also available in pre-dispersion form. The following are the common types of matting agent:

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paint

In this part 2, we will feature 2 formulations. The first formula is strippable fluorescence color thermoplastic acrylic. This system required a 2 coats system, the base coat consist of the fluorescence pigment and a clear coat onto  the fluorescence base coat.

Fluorescence Coat

The base coat formula :

Base coat
Material Supplier Amount
Paraloid F-10(40% solid) Rohm & Haas 48
Dispersing additive various 1
Fluorescence pigment various 38
Xylene various 13
  Total 100

 

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aerosol.jpgThis is the first part of a 2 parts series of the thermoplastic acrylic. The suggested formula given below can be use for aerosol or normal air spray application, with adjustment on the viscosity to suit the respective application requirement.

3 formula, consist of clear coat, white top coat and metallic coat will be featured in this Part I. Please find below the clear coat formula:

Thermoplastic Acrylic Clear Coat

Ingredient

Supplier

Amount%

Paraloid B66 (55% solvent) Rohm & Haas               40                  
PM Solvent various 10
Toluene various 8
Xylene various 42

Total

  100

 

Note: Load and mix the above ingredients by sequence and stirred homogeneously for at least 15 minutes.

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COLOR CHANGING PAINT TECHNOLOGY

Would you like your paint to be able to change it color under specified condition?
How about market this paint color change properties as value added feature for your paint???

Sound too good to be true? Well, color changing technology is nothing new. What cause the color change?
The main secret to the color change come from the specific pigment properties. The color change is not because the pigment show poor durability or chalking, the color change is because the pigment react to certain condition apply to them.

There are 3 main types of pigment that involve in the color change technology:

1) Photochromic pigment
2) Thermochromic pigment
3) Electrochromic pigment

Photochromic pigment is sensitive to light. A photochromic pigment  will change from transparent to a color when
it is exposed to light, and revert to transparency when the light is dimmed of blocked. Reversible photochromic work by changing their chemical structure after absorbing UV light. The UV light causes the photochromic to absorb color and then change back to clear when the UV source is removed.They can be cycle thousands of times depending upon the application. This pigment can also change from one colour to a different colour by combination with a permanent pigment. The reversible photochromic has been in the color changing lenses for sunglasses. They are also found in the novelty application such as cosmetics, toy and industry applications including paint. They can be applied in the smart energy efficient windows and information display panels. They can control visible light and solar radiation levels passing through them and by carefully formulating, we can regulate the illumination levels, heat gain and heat loss and  this help to better control the interior temperature of a building.

Thermochromic paint and coating change conformation when certain temperature is applied that cause them to change color. This materials have been used in temperature sensitive tape. The color change can be reversible and irreversible respectively.

Electrochromic pigment is apply to paint that change its color with the help of electricity. In short, the paint required an electrical current to change color. The electric current creates special crystals at the surface that can change color depending on the voltage. This only works on metal because a conductive material is required. When the power is removed from the paint, the color change back to its original color. This technology can create every color the human eye can differentiate, with the simple flip of a switch. This technology has been apply to car paint. Would like you car to change color at your wish? This sound like the James Bond 007′ car that can change color.

Tip#1: Try those color change pigment with normal pigment to create different color changing shade.

Tip#2: If durability is required, please use color change pigment instead of dye.

Tip#3: Study how many cycle the pigment can change its color before launching your products.

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